Understanding hopping transport and thermoelectric properties of conducting polymers
نویسندگان
چکیده
منابع مشابه
Thermoelectric properties of conducting polymers
According to different sources, from forty to sixty percent of the overall energy generated in the world today is squandered in waste heat. The existing energy conversion technologies are either close to their efficiency limits or too costly to justify their implementation. Therefore, the development of new technological approaches for waste heat recovery is highly demanded. The field of thermo...
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Configurational fluctuations of conducting polymers in solution can bring into proximity monomers which are distant from each other along the backbone. Electrons can hop between these monomers across the “bridges” so formed. We show how this can lead to (i) a collapse transition for metallic polymers, and (ii) to the observed dramatic efficiency of acceptor molecules for quenching fluorescence ...
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Ladder-type "torsion-free" conducting polymers (e.g., polybenzimidazobenzophenanthroline (BBL)) can outperform "structurally distorted" donor-acceptor polymers (e.g., P(NDI2OD-T2)), in terms of conductivity and thermoelectric power factor. The polaron delocalization length is larger in BBL than in P(NDI2OD-T2), resulting in a higher measured polaron mobility. Structure-function relationships ar...
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ژورنال
عنوان ژورنال: Physical Review B
سال: 2015
ISSN: 1098-0121,1550-235X
DOI: 10.1103/physrevb.92.035201